40nm BSI CMOS Image SensorPreview

Implant Oxide Removal

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Sacrificial Oxidation

SACOX Removal
69Sacrificial Oxidation70SACOX Removal71Thin Gate Oxide Growth72Nitride Hard Mask Deposition73Pre Litho Cleaning74Thick Gate Oxide - Photo75Nitride Hard Mask Etch76Ashing & Strip/Clean77Thick Gate Oxide Growth78Nitride Hard Mask Removal

Process Cross-Section

DGOX · DGOX1 · Sacrificial Oxidationsacrificial ox (SiO2, thermal)VT adjust (11B+, periphery channel)SiO2 liner (SACVD)SiO2 (SACVD bulk fill)n+ N-well contact (31P+)p+ surface passivation (10B+)Liner SiO2 (RTP thermal)P-well (pixel array, 11B+)P-well (periphery, 11B+)PD N-well (31P+)SiNN-well (periphery, 31P+)SiP-well (implanted region)

Step highlight

Ultimately, optimizing the final Si/SiO2 interface quality minimizes interface trap states and fixed charges, preventing flat-band voltage shifts and carrier mobility degradation .

In depth

After the NMOS VT Adjust implant and subsequent stripping steps, the exposed silicon surface retains physical damage

and potential contamination . To ensure the integrity of the critical gate dielectric grown in subsequent steps, the process flow introduces a Sacrificial Oxidation (SACOX) step . As described in , the formation of a sacrificial oxide layer involves the partial oxidation of the exposed silicon material, which converts it into silicon dioxide. This step intentionally consumes the uppermost layer of the silicon substrate, which harbors implantation-induced lattice defects and residual contaminants . By subsequently removing this sacrificial layer in the DGOX module, the surface is left smooth and pristine, preparing an optimal foundation for the Thin Gate Oxide Growth . The core physical mechanism of sacrificial oxidation is the thermal diffusion-limited reaction between silicon and an oxygen-containing ambient to form a stable SiO2 film . During thermal oxidation, oxidant molecules diffuse through the growing oxide layer to react with silicon atoms directly at the Si/SiO2 interface . This chemical reaction inherently consumes a portion of the silicon substrate, essentially modifying the surface topography in a highly controlled manner . Furthermore, the thermal energy applied during this oxidation process allows for the localized annealing of shallow structural defects generated by prior heavy ion bombardments . Because the oxidation rate is sensitive to the local stress or damage state of the silicon lattice, the process actively smoothens the surface, repairing atomic-scale roughness induced by preceding steps . Thermal oxidation is strategically selected over chemical vapor deposition for this step because it relies on the direct consumption of the substrate, which is strictly required to remove the damaged silicon layer . The process kinetics are governed by the ambient gas composition and temperature, which determine the availability of reactive oxygen species at the interface . Parameter interactions dictate a strict thermal budget trade-off; higher temperatures exponentially increase the oxidation rate and promote better lattice defect annealing, but they also drive the undesirable diffusion of newly implanted dopants . Therefore, the thermal cycle must be meticulously balanced to achieve sufficient silicon consumption without compromising the precise extrinsic carrier concentration profiles required for transistor operation . Ultimately, optimizing the final Si/SiO2 interface quality minimizes interface trap states and fixed charges, preventing flat-band voltage shifts and carrier mobility degradation . In 40nm CMOS image sensor technologies, pixel performance is exceptionally sensitive to dark current, making the structural perfection of the silicon surface paramount . Any residual surface roughness or trapped interface charges act as active generation-recombination centers, severely degrading the sensor's low-light sensitivity . Moreover, as the physical thickness of the subsequent gate oxide is scaled down for the 40nm node, the dielectric becomes highly vulnerable to localized thinning or quantum tunneling leakage initiated by microscopic substrate asperities . Thus, the sacrificial oxidation step acts as a critical reliability safeguard, ensuring that the subsequently grown thin gate oxide achieves stringent gate oxide integrity without introducing excessive thermal budgets that could smear advanced logic junctions .

Risks & Challenges

  • [High] Dopant Redistribution: The thermal budget of the SACOX process drives the diffusion of recently implanted NMOS VT dopants . If the temperature is excessive, dopants can diffuse out of the intended channel region, fundamentally altering the impurity-dominated extrinsic state and shifting the transistor threshold voltage .
  • [High] Incomplete Surface Smoothening: If the sacrificial oxide thickness is insufficient, the process will fail to fully consume the silicon lattice layer damaged by prior implant steps . This residual roughness acts as a local electric field multiplier, significantly degrading the breakdown voltage and long-term reliability of the subsequent thin gate oxide .
  • [Medium] Oxidation-Induced Stacking Faults (OISF): During thermal oxidation, the volume expansion at the Si/SiO2 interface injects silicon interstitials into the bulk substrate . In the presence of pre-existing implant damage, these interstitials nucleate extended structural defects that serve as generation centers, drastically increasing dark current in the image sensor pixels .
  • [Low] Excessive Silicon Consumption: An overly aggressive oxidation process consumes too much active silicon substrate due to the diffusion-limited reaction kinetics . This unexpected loss of the carefully engineered channel region alters the physical depth of the previously implanted dopant profiles, compromising device operation .

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Related steps

  • SACOX Removal
  • Thin Gate Oxide Growth
  • Nitride Hard Mask Deposition
  • Pre Litho Cleaning
  • Thick Gate Oxide - Photo
  • Nitride Hard Mask Etch