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Ta-based liner deposition

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Cu Seed deposition

Metal 1 Cu deposition
151METAL 1 TRENCH - Photo152PMD 5 Oxide Etch153PMD 4 Oxide Etch154Ashing & Strip/Clean155Ta-based liner deposition156Cu Seed deposition157Metal 1 Cu deposition158Cu CMP159Ta-based liner CMP160Post CMP Cleaning161ILD 1-1 SiCN Barrier Deposition162ILD 1-2 SiO2 Gap-Fill Deposition163Pre Litho Cleaning164VIA 1 - Photo165ILD 1-2 Oxide Etch166ILD 1-1 SiCN Etch167Ashing & Strip/Clean

Process Cross-Section

MET1 · Cu Seed DepositionTiSi (low-temp anneal)n- LDD (31P+, self-aligned)P-pinning (11B+)P+ VSS contact (11B+)FD node (31P+)VT adjust (11B+, periphery channel)SiO2 liner (SACVD)SiO2 (SACVD bulk fill)n+ S/D (31P+)n+ N-well contact (31P+)p+ surface passivation (10B+)Liner SiO2 (RTP thermal)P-well (pixel array, 11B+)P-well (periphery, 11B+)PD N-well (31P+)N-well (periphery, 31P+)SiP-well (implanted region)CuPMD 5 (SiO2)TaPMD 4 (SiO2)MET0 (W)PMD 3 (SiO2 · CMP overburden)W (contact fill)PMD 2 (SiO2 · body segment)TiN (barrier)Ti (adhesion)Ti/TiN linerPMD 1 (SiO2 · bottom segment)CESL 2 (SiNO)SiNCESL 1 (SiN)PolySWS pad ox (SiO2, PECVD)gate ox (SiO2, thermal)IO/HV gate ox (SiO2; relative thickness shown schematically; IO device not shown in this cross-section)

Step highlight

Copper is uniquely selected as the seed material because it provides a chemically identical and lattice-matched foundation for the bulk copper fill, minimizing interfacial electrical resistance and preventing electromigration vulnerabilities .

In depth

The Cu Seed deposition step in the MET1 module serves

as the critical bridge between the highly resistive Ta-based diffusion barrier and the subsequent bulk copper electroplating process . Because electrochemical deposition relies on a continuous, highly conductive surface to serve as the cathode for uniform current distribution, a high-quality seed layer is mandatory . Without this seed layer, the subsequent plating process cannot initiate properly, leading to discontinuous growth or catastrophic voiding within the interconnect structures . Placed immediately after the Ta-based liner, this step provides the necessary nucleation sites for the electroplated copper to grow . What distinguishes this MET1 seed deposition from the analogous steps in higher metal layers (such as steps #172, #188, etc .) is the severity of the structural geometry: MET1 typically features the tightest pitch and most aggressive aspect ratios in the back-end-of-line (BEOL) stack (Engineering Practice). Consequently, the MET1 seed layer must be exceptionally thin to prevent premature pinch-off of the narrow trenches, yet continuous enough to guarantee an uninterrupted electrical path from the feature bottom to the wafer edge . The physical mechanism of this deposition relies primarily on Physical Vapor Deposition (PVD), where metal target atoms are sputtered in a vacuum and directed toward the wafer surface . The vapor pressure of the metal and the precisely controlled vacuum conditions dictate the transport and arrival of copper atoms . During PVD, adjusting the wafer bias establishes a dynamic balance between ion directionality and neutral atom deposition, which is essential for achieving adequate coverage on both the bottom and sidewalls of high-aspect-ratio features . However, purely conformal PVD is difficult in nanoscale trenches due to shadowing effects (Engineering Practice). To mitigate this, thermally activated surface diffusion mechanisms can be employed, where higher temperatures drive the migration of copper atoms from the sidewalls down to the trench bottom, driven by surface energy and chemical potential gradients . This localized pre-filling effectively reduces the aspect ratio, greatly enhancing the success rate of the subsequent electroplating step . Copper is uniquely selected as the seed material because it provides a chemically identical and lattice-matched foundation for the bulk copper fill, minimizing interfacial electrical resistance and preventing electromigration vulnerabilities . However, ultrathin PVD copper layers deposited on dissimilar materials like Ta-based liners often suffer from poor wetting and tend to form isolated particulate morphologies rather than smooth, continuous films . To suppress this agglomeration, interfacial reaction kinetics and surface mobility must be carefully managed through temperature control and precise biasing . Furthermore, queue times between the seed deposition and the plating step must be strictly limited; prolonged exposure to ambient conditions causes the copper seed to oxidize, which consumes the effective thickness of the continuous metal and drastically reduces the nucleation density during electroplating . In scenarios where PVD reaches its physical limits, introducing an ultrathin Chemical Vapor Deposition (CVD) or Atomic Layer Deposition (ALD) liner prior to or alongside the seed can improve the effective continuity and wetting of the copper, restoring dense growth . At the 40nm technology node, the interplay between device performance and physical scaling limits becomes highly pronounced . The continuous shrinking of interconnect dimensions means that standard PVD parameters will easily cause excessive field accumulation and overhang at the trench opening, blocking the subsequent fill . Conversely, reducing the nominal deposition thickness too much risks forming a discontinuous seed that acts as an open circuit during plating . This fundamental geometric and thermodynamic trade-off forces process engineers to carefully co-optimize wafer bias and deposition temperature to maintain yield . By ensuring a flawless MET1 fill, this step ultimately prevents resistance-capacitance (RC) delays from compromising the switching speed and power consumption of the underlying scaled MOSFETs .

Risks & Challenges

  • [High] Seed Layer Discontinuity and Agglomeration: When the physical vapor deposited (PVD) copper seed is excessively thin on the Ta-based liner, it fails to form a continuous film and instead coalesces into isolated particulate islands due to surface energy mismatches . This discontinuity leads to highly localized and irregular electroplating, which eventually causes large voids at the barrier/copper interface .
  • [High] Trench Pinch-off (Overhang): Excessive copper deposition on the field regions and upper corners of the interconnect trenches can physically block the feature opening . This geometric shadowing prevents the electroplating chemistry from reaching the via bottom, resulting in massive center voids or "seams" in the final copper line .
  • [Medium] Seed Oxidation (Queue Time Degradation): An extended queue time between the Cu seed deposition and the subsequent electroplating step exposes the highly reactive ultrathin copper to trace oxygen or moisture . This oxidation consumes the pure metallic copper, drastically reducing the effective conductive thickness and leading to coarser, separated deposits during the electroplating phase .
  • [Low] Ta Liner Resputtering and Contamination: The application of an excessively high wafer bias during the PVD seed step, intended to improve bottom via coverage, can cause highly energetic incoming ions to resputter the underlying Ta liner . This not only damages the diffusion barrier's integrity but can also mix Ta into the copper seed, increasing the electrical resistance of the final interconnect .

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Related steps

  • METAL 1 TRENCH - Photo
  • PMD 5 Oxide Etch
  • PMD 4 Oxide Etch
  • Ashing & Strip/Clean
  • Ta-based liner deposition
  • Metal 1 Cu deposition