40nm BSI CMOS Image SensorPreview

As-doped PolySi deposition

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PolySi Anneal

Pre Litho Cleaning
79As-doped PolySi deposition80PolySi Anneal81Pre Litho Cleaning82Gate Formation - Photo83PolySi - Etch84Ashing & Strip/Clean

Process Cross-Section

GATE · G2 · PolySi Anneal (Dopant Activation)Polygate ox (SiO2, thermal)IO/HV gate ox (SiO2; relative thickness shown schematically; IO device not shown in this cross-section)VT adjust (11B+, periphery channel)SiO2 liner (SACVD)SiO2 (SACVD bulk fill)n+ N-well contact (31P+)p+ surface passivation (10B+)Liner SiO2 (RTP thermal)P-well (pixel array, 11B+)P-well (periphery, 11B+)PD N-well (31P+)SiNN-well (periphery, 31P+)SiP-well (implanted region)

Step highlight

the thermal cycle must provide sufficient kinetic energy for bulk dopant diffusion while satisfying the boundary conditions of the gate stack geometry .

In depth

The PolySi Anneal step immediately follows the deposition of Arsenic-doped polycrystalline silicon and precedes the photolithography and etching

modules for gate formation . Its primary function is to thermally activate the implanted or in-situ incorporated dopants within the gate electrode, transforming the highly resistive as-deposited layer into a highly conductive electrode . In modern CMOS integration, heavily doped polysilicon is utilized as the gate material because it withstands high-temperature processing and its work function can be customized via doping to achieve symmetrical threshold voltages for both NMOS and PMOS devices . For an n-type gate, activating the Arsenic dopants shifts the Fermi level toward the conduction band edge, aligning the effective work function with the silicon electron affinity . Proper execution of this step guarantees uniform carrier concentration across the gate stack before it is patterned into isolated transistor lines . The physical mechanism of this anneal relies on thermal energy to drive dopant atoms into substitutional lattice sites within the silicon crystal structure, converting them into electrically active donors . According to Fermi-Dirac statistics, introducing these shallow donor impurities allows electrons to be thermally excited at energies far below the intrinsic bandgap, vastly increasing the free carrier concentration . Simultaneously, the thermal budget promotes structural rearrangement of the polysilicon matrix, an essential step to mitigate the inherently high resistance of polycrystalline gate materials discussed in . This dopant diffusion is critical to ensuring that a high concentration of active Arsenic reaches the immediate interface between the polysilicon and the underlying gate dielectric . If the interface is insufficiently doped, a parasitic depletion region forms within the gate during device operation, effectively increasing the equivalent oxide thickness (EOT) and severely degrading the drive current capability of the field-effect transistor . Thus, the thermal cycle must provide sufficient kinetic energy for bulk dopant diffusion while satisfying the boundary conditions of the gate stack geometry . The selection of annealing parameters involves a careful balance between maximizing dopant activation and minimizing detrimental thermal degradation of the underlying gate oxide interface . Advanced thermal cycles are designed to rapidly achieve the high temperatures necessary for maximal activation while restricting the time available for dopant diffusion, thereby preserving precise doping boundaries . As device dimensions scale, the electric field distribution across the inversion layer becomes increasingly sensitive to the gate structure and charge distribution . Excessive thermal budgets can lead to interfacial instability and the growth of uncontrolled transition layers, which compromises the scaling of the EOT . Conversely, an insufficient temperature or time prevents complete lattice repair and fails to lower the sheet resistance to the levels required for high-speed switching operations . Therefore, the temperature and ramp rates are co-optimized with the Arsenic concentration to ensure complete physical compatibility in downstream processes, such as the selective formation of metal silicides on the patterned gate . In a 40nm CMOS Image Sensor (CIS) technology, stringent control over the thermal budget is particularly critical because excessive heat can exacerbate defect states and junction leakage in the highly sensitive pixel array . The dual-oxide integration scheme—typically utilizing a thick gate oxide for high-voltage pixel transistors and a thin oxide for logic—mandates an anneal process that activates dopants uniformly across varying step heights without degrading the respective dielectric integrity . By ensuring robust work-function setting and preventing Fermi-level pinning at this stage, the subsequent formation of the image sensor's readout circuitry can maintain strict threshold voltage uniformity across the die .

Risks & Challenges

  • [High] Poly-Depletion from Incomplete Activation: Insufficient thermal budget prevents the Arsenic dopants from fully diffusing to and activating at the polysilicon-oxide interface . During device inversion, this lack of free carriers creates a depletion layer inside the poly-Si gate . This depletion layer acts as a series capacitor, inadvertently increasing the effective equivalent oxide thickness (EOT) and degrading the transistor's drive current .
  • [Medium] Dopant Penetration through Gate Dielectric: Excessive annealing temperature or duration provides too much thermal energy, driving Arsenic dopants through the thin gate oxide and into the underlying silicon channel . This unintended channel doping alters the local Fermi level and shifts the threshold voltage away from its designed target . Furthermore, structural damage to the dielectric degrades the ideal oxide-silicon interface, increasing surface scattering and reducing channel mobility .
  • [Medium] Dielectric Interface Degradation and Regrowth: High-temperature processing can trigger interfacial reactions between the polysilicon and the gate oxide, particularly if residual species from previous processing steps are present . Thermal annealing can cause oxygen redistribution at the interface, forming parasitic low-k transition layers . The growth of these unintentional interfacial layers compromises the EOT scaling limits and introduces trap states that cause threshold voltage drift and reliability failures .
  • [Low] Dopant Segregation at Grain Boundaries: During the structural relaxation of the polysilicon, Arsenic atoms may preferentially segregate to the grain boundaries rather than occupying active lattice sites within the grains . Because dopants trapped at grain boundaries are electrically inactive, the overall free carrier concentration drops . This localized depletion increases the gate sheet resistance, adding to the RC delay of the device and limiting high-frequency performance .

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Related steps

  • As-doped PolySi deposition
  • Pre Litho Cleaning
  • Gate Formation - Photo
  • PolySi - Etch
  • Ashing & Strip/Clean