a soft bake drives out residual developer solvents and stabilizes the polymer matrix, providing the structural integrity required to prevent premature deformation before the high-temperature reflow stage .
Following the fabrication and thermal curing of the Color Filter Arrays (CFA) and the subse
quent deposition of a planarizing base layer, the Upper On-Chip Lens (UOCL) Coat/Expose/Develop/bake step is executed . The primary function of the Upper OCL is to gather and focus incident light directly into the underlying pinned photodiode, thereby maximizing the pixel's quantum efficiency and minimizing signal loss . Unlike the preceding CFA patterning steps, which utilize dye-doped polymers designed to absorb specific spectral bands to establish color [P3, T2], the UOCL process strictly employs highly transparent materials to ensure broad-spectrum photon transmission . This step uses photolithography to define the pre-reflow footprint and volume of the lens material, creating discrete resin pillars that will subsequently be shaped into convex lenses during the reflow process . This step is distinct from the sacrificial Lower OCL, as the Upper OCL forms the permanent, final light-gathering interface at the top of the backside-illuminated (BSI) optical stack . The physical mechanism of this step relies on the precise application and photochemical transformation of a photosensitive polymer resin . First, spin-coating distributes a uniform layer of the liquid resin across the wafer, where the final coated thickness fundamentally dictates the volume of the lens . During ultraviolet exposure, the mask defines the lateral dimensions (critical dimension, CD) and the gaps between adjacent pixels, initiating photochemical crosslinking or chain scission depending on the resist tone . The development process then selectively removes the highly soluble regions to isolate the individual resin blocks (Engineering Practice). Finally, a soft bake drives out residual developer solvents and stabilizes the polymer matrix, providing the structural integrity required to prevent premature deformation before the high-temperature reflow stage . The selection of the microlens resin is driven by its optical properties, specifically requiring high transmittance across the visible spectrum and a tailored refractive index—typically in the range of 1.6 to 1.8—to achieve sufficient refractive power at the lens-air or lens-protective-layer interface . The interaction between the coated film thickness and the exposed pillar CD is tightly controlled, as these parameters jointly determine the eventual radius of curvature of the reflowed lens . Optical metrology, utilizing scatterometry and diffraction models, is heavily employed at this stage to measure the pre-reflow profile and monitor process variations, ensuring sub-nanometer precision in volume control . If the gap separating adjacent pillars is patterned too narrowly, the subsequent reflow will cause the lenses to merge; conversely, a gap that is too wide diminishes the pixel fill factor and introduces optical dead zones that degrade sensitivity . In nanoscale Backside-Illuminated (BSI) CMOS image sensor technology, the heavily scaled pixel pitch places stringent demands on the UOCL patterning step . As feature sizes shrink into the deep sub-micron regime, the alignment overlay of the microlens to the underlying photodiode and color filter becomes highly critical to prevent incident light from spilling into adjacent pixels [P3, P4]. The BSI architecture inherently places the microlens physically closer to the photodetector by removing the frontside metallization stack, permitting a wider optical acceptance angle . However, to fully leverage this architectural advantage, the UOCL Coat/Expose/Develop/bake step must produce exceptionally uniform resin pillars to ensure perfectly symmetric focal profiles across the entire high-density pixel array .
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