If the radical flux is too high, the polymer layer thickens excessively, exponentially reducing the etch rate and leading to a complete etch stop condition .
The CESL 2 - Etch step occurs immediately after the bulk Pre-Metal Dielectric (PMD) oxide has been anisotropically etched to open the conta
ct holes . In the 40nm BSI CMOS Image Sensor flow, the contact module utilizes a multi-layer Contact Etch Stop Layer (CESL) scheme to provide both robust etch stopping capabilities and highly localized channel strain . Because the preceding PMD etching processes use high-selectivity fluorocarbon plasmas designed to stop efficiently on the uppermost nitride layer, this specific step is required to break through the upper CESL (CESL 2) before a separate step handles the lower CESL (CESL 1) . This sequential multi-step etching ensures that the underlying silicide and epitaxial source/drain regions are not exposed prematurely, thereby protecting the sensitive active areas from severe over-etching damage during the deep PMD clearance . The etching of the amorphous hydrogenated silicon nitride (a-SixNyHz) CESL relies on reactive ion etching (RIE) utilizing a carefully balanced fluorocarbon plasma . The fundamental mechanism involves the continuous deposition of a fluorocarbon (CF) polymer film on the nitride surface, coupled with simultaneous physical ion bombardment that drives the chemical removal of the material . Unlike silicon dioxide, which releases oxygen during etching to volatilize the polymer, silicon nitride lacks an internal oxygen source, causing the CF film to grow thicker and dissipate incident ion energy . To sustain the etch process without stopping, the reactive species flux—particularly the CFx radicals—must be precisely tuned against the ion energy to penetrate the steady-state polymer layer . The reaction ultimately forms volatile fluorinated byproducts, clearing the CESL 2 layer strictly within the defined geometric boundaries of the contact hole (Engineering Practice). A highly directional, anisotropic dry etch method is selected for this step to maintain the critical dimensions of the high-aspect-ratio contact holes defined during the PMD etch . The plasma chemistry parameters, such as the ratio of polymerizing gases to inert carriers and trace oxidants, are dynamically adjusted to modulate the transient CF polymer thickness . If the radical flux is too high, the polymer layer thickens excessively, exponentially reducing the etch rate and leading to a complete etch stop condition . Conversely, inadequate polymer formation degrades the etch selectivity to the underlying CESL 1 layer or adjacent spacer structures, leading to uncontrolled profile bowing or spacer erosion . Furthermore, the choice of process pressure and radio-frequency (RF) bias voltage directly dictates the mean free path and the perpendicular electric field, which physically govern the trajectory and energy of the bombarding ions (Engineering Practice). In the 40nm node, continuous geometrical scaling drastically reduces the available contact area, which inversely increases the intrinsic contact resistance . Therefore, the CESL 2 etch must be executed with minimal lateral isotropic etching to prevent the enlargement of the contact critical dimension (CD), which could easily cause fatal electrical shorts between the contact metal and the adjacent metal gate . Because the PECVD SiN CESL acts as a primary source of mechanical strain to physically alter the silicon lattice constant and enhance channel carrier mobility, preserving the structural integrity of the unetched film surrounding the contact hole is paramount . The dual-CESL step sequence allows the plasma parameters to be sequentially stepped down in chemical aggressiveness, ensuring that the final contact interface—which may utilize specialized sloped or recessed profiles to maximize electrical contact area—remains free of plasma-induced crystalline damage .
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